For the creme fraiche: In a medium bowl, whisk the whipping cream and sour cream together until smooth. Cover and let it sit on the counter at room temp for at least 12 hours. Refrigerate until ready to use the next day.
For the cake: Preheat the oven to 350 degrees. Grease and flour your sheet pan or jelly roll pan. In a small bowl or measuring cup, combine the buttermilk, poppyseeds and 4 teas. of orange zest. Let stand while you:
Sift flour, baking soda and salt into a medium bowl. Using stand mixer cream butter and both sugars in a large bowl until fluffy. Beat in egg yolks one at a time, and vanilla. Mix in dry ingredients alternating with buttermilk mixture, ending with dry ingredients. Using clean dry beaters, beat the egg whites in another bowl until stiff and fold into the batter. Pour batter into prepared pan, smooth the top and sprinkle with cinnamon.Bake until a tooth pick into the center comes out clean: 20 to 24 minutes. Cool in the pan. Melt 8 oz. of semi sweet chocolate in the microwave on high, 20 seconds at a time, stirring in between until smooth. Let the chocolate cool slightly and add to the cream fraiche with 2 teaspoons of orange zest and orange liquor (if using) and whisk until smooth. Chill in refrigerator until cake has cooled
Cut the cake into 4 pieces. You can set aside one piece for eating later, and make a 6 layer cake, or use all the cake and have 8 layers. Using a serrated knife, cut the pieces in half horizontally, forming 6(8) layers. Place one layer on your cake plate and spread about 1/4 cup of the orange/chocolate fraiche evenly over the layer. Repeat with the other 5 layers, ending with a cut side down. Smooth the remaining creme fraiche over the the top and sides of the cake. Refrigerate until the filling is firm, about 2 hours.
For the chocolate ganache: Put the semi sweet and unsweetened chocolate in a heat proof bowl. . Put the cup of cream on the stove in a small pot with the TBLS of sugar and bring to a boil. Pour the hot cream over the chocolate and let it sit for 5 minutes. Then take your whisk and stir until the ganache has a smooth consistency. Let it sit until it comes to room temp.
Take the cake out of the refrigerator and smooth a layer of ganache over the entire cake. Decorate with orange slices. Refrigerate until ganache has set. Cover and keep in the refrigerator until 30 minutes before serving. Cut down the middle, and cut 8 slices from each side (see post photo for example).